| Title of Article |
One-Pot Multiple MOF Formation: Concomitant Generation of Structural Isomers or of Drastically Distinct Materials |
| Date of Acceptance |
28 May 2014 |
| Journal |
| Title of Journal |
European Journal of Inorganic Chemistry |
| Standard |
ISI |
| Institute of Journal |
John wiley & Sons. Inc |
| ISBN/ISSN |
- |
| Volume |
- |
| Issue |
- |
| Month |
- |
| Year of Publication |
2014 |
| Page |
- |
| Abstract |
Solvothermal reaction of 2,5-dihydroxyterephthalic acid (H2dhtp) and magnesium(II) nitrate in DMF leads to the simultaneous formation of two structural isomers or MOFomers, namely the lvt network Mg(dhtp)(dmf)2 (1) and the compound Mg3(dhtp)3(dmf)6·0.75H2O (2) with the pcu alpha-Po primitive cubic topology. The same reaction conditions using anganese(II) nitrate and terephthalic acid (H2tp) result in the concomitant generation of two drastically different MOFs, i.e. Mn2(tp)2(dmf)2 (3) and [Mn(HCOO)3][NC2H8] (4), whose formato ligands and N.N-dimethylammonium cations arise from DMF degradation. |
| Keyword |
One-pot synthesis, Multiple MOF formation, structural isomers |
| Author |
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| Reviewing Status |
มีผู้ประเมินอิสระ |
| Status |
ได้รับการตอบรับให้ตีพิมพ์ |
| Level of Publication |
นานาชาติ |
| citation |
false |
| Part of thesis |
true |
| Attach file |
|
| Citation |
0
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Publication
Journal Publication
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