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Publication
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| Title of Article |
Thermally Induced Single-Crystal-to-Single-Crystal Transformation and Heterogeneous Catalysts for Epoxidation Reaction of Co(II) Based Metal−Organic Frameworks Containing 1,4-Phenylenediacetic Acid |
| Date of Acceptance |
3 March 2017 |
| Journal |
| Title of Journal |
CRYSTAL GROWTH & DESIGN |
| Standard |
SCOPUS |
| Institute of Journal |
ACS Publications |
| ISBN/ISSN |
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| Volume |
17 |
| Issue |
4 |
| Month |
March |
| Year of Publication |
2017 |
| Page |
1824-1835 |
| Abstract |
Four new metal−organic frameworks (MOFs)
based on 1,4-phenylenediacetic acid (1,4-H2phda),
[Co(1,4-phda)(4,4′-bpa)] (1), [Co(1,4-phda)(4,4′-bpp)] (2),
[Co(1,4-phda)(4,4′-bpa)(H2O)2] (3), and [Co(1,4-phda)-
(4,4′-bpa)] (3a) (4,4′-bpa = 1,2-bis(4-pyridyl)ethane and
4,4′-bpp = 1,3-bis(4-pyridyl)propane) were successfully
synthesized. The various synthetic methods play an important
role in the formation of diverse structural frameworks.
Compound 1 shows a 3D framework, while 2, 3, and 3a exhibit 2D layered MOFs with different architectures. The irreversible
thermally induced single-crystal-to-single-crystal transformation with chromotropism from 3 to 3a was observed, which was
established by the breakage and reformation of coordination bonds around Co(II) centers. The orientation of coordinated
4,4′-bpa ligand and conformation of 1,4-phda ligand play a key role on pore opening in 3 and pore closing in 3a. Furthermore,
the functional properties as heterogeneous catalysts of these MOFs including epoxidation of alkenes and photocatalytic
performance for MB degradation have been investigated. The heterogeneous catalytic properties of 1, 2, and 3a exhibit high
catalytic activity with good catalyst stability. |
| Keyword |
Metal-organic framework, epoxidation of alkenes, photocatalytic, single-crystal-to-single-crystal transformation, cobalt(II), 1,4-phenylenediacetic acid, heterogeneous catalysis |
| Author |
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| Reviewing Status |
มีผู้ประเมินอิสระ |
| Status |
ตีพิมพ์แล้ว |
| Level of Publication |
นานาชาติ |
| citation |
true |
| Part of thesis |
true |
| Attach file |
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| Citation |
0
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Journal Publication
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