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Publication
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| Title of Article |
Enhanced photocatalytic performance of ZnO/Bi2WO6 heterojunctions toward photodegradation of fluoroquinolone-based antibiotics in wastewater |
| Date of Acceptance |
8 February 2021 |
| Journal |
| Title of Journal |
Journal of Physics and Chemistry of Solids |
| Standard |
SCOPUS |
| Institute of Journal |
Elsevier Ltd. |
| ISBN/ISSN |
00223697 |
| Volume |
2021 |
| Issue |
153 |
| Month |
February |
| Year of Publication |
2021 |
| Page |
109995 |
| Abstract |
The present work focused on development of a new ZnO/Bi2WO6 heterojunction photocatalyst with a high solar-light-responsive property and a promising charge carriers separation efficiency. A facile solvothermal route for preparation of novel ZnO/Bi2WO6 heterojunction based on well dispersion of flower-like Bi2WO6 on the surface of rod-like ZnO has been demonstrated. The prepared photocatalyst exhibited the orthorhombic phase of Bi2WO6 (BWO) together with the hexagonal phase of ZnO. The 0.05ZnO/BWO heterojunction photocatalyst with the smallest size and lowest PL intensity, implying highest electron-hole separation efficiency, exhibited the highest photoactivity of 87%, 85%, and 84%, respectively, toward degradation of NOR, CIP, and OFL antibiotics. The photocatalyst also provided a very high solar-light-driven photodegradation performance of 97% toward degradation of NOR antibiotic for 120 min. The generation of the ZnO/Bi2WO6 heterostructures is the key factor for an enhanced photocatalytic performance in the resultant photocatalyst. The photodegradation of the fluoroquinolone antibiotics followed the first-order reaction. Photogenerated hole plays an important role in removal of NOR antibiotic. The chemical structure of the 0.05ZnO/BWO heterojunction photocatalyst remained stable after photodegradation. The prepared photocatalyst still shows high efficiency after the fifth run implying its promising structural stability and reusability. This work demonstrates a very high potential of the prepared heterojunction 0.05ZnO/BWO photocatalyst for detoxification of fluoroquinolone-based antibiotics in wastewater. |
| Keyword |
ZnO/Bi2WO6, Photodegradation, Antibiotics, Solar light, Heterojunction |
| Author |
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| Reviewing Status |
มีผู้ประเมินอิสระ |
| Status |
ตีพิมพ์แล้ว |
| Level of Publication |
นานาชาติ |
| citation |
true |
| Part of thesis |
true |
| ใช้สำหรับสำเร็จการศึกษา |
ไม่เป็น |
| Attach file |
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| Citation |
0
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Journal Publication
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