Title of Article |
Influence of an SCN- moeity on the electronic properties of g-CsPb(SCN)xBr3-x and the performance of carbon-based HTL-free g-CsPb(SCN)xBr3-x perovskite solar cells |
Date of Acceptance |
18 November 2020 |
Journal |
Title of Journal |
Journal of Materials Science: Materials in Electronics |
Standard |
SCOPUS |
Institute of Journal |
Springer |
ISBN/ISSN |
1573-482X |
Volume |
2021 |
Issue |
32 |
Month |
มกราคม 63 |
Year of Publication |
2020 |
Page |
1557-1569 |
Abstract |
A CsPbBr3 film was prepared by the hot-casting method from a mixed CsBr and PbBr2 solution with an orthorhombic-phase (c) CsPbBr3 perovskite structure. cCsPbBr3 film has a yellow color with a bandgap energy of 2.32 eV. The low SCNdopant level forming CsPb(SCN)xBr3-x (x = 0.0625, 0.125, 0.01875, 0.25 and 0.5) films maintains an orthorhombic CsPb(SCN)xBr3-x structure with a film bandgap of 2.32-2.34 eV. The calculated bandgap of the optimized c-CsPb(SCN)xBr3-x structures slightly changed with SCN- dopant levels from x = 0 to x = 0.5. A carbon-based hole transport layer (HTL)-free c-CsPb(SCN)0.25Br2.75 solar cell delivers the highest efficiency of 4.5% under six conditions compared to a carbon-based HTL-free pure c-CsPbBr3 solar cell with an efficiency of 3.89%. The stability of the carbon-based HTL-free c-CsPb(SCN)0.25Br2.75 solar cell is better than that of the carbon-based HTL-free pure c-CsPbBr3 solar cell with efficiency retention of 88.96% and 61.86% of their initial values, respectively, after a 30-day testing period.
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Keyword |
perovskite solar cells, CsPbBr3 |
Author |
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Reviewing Status |
มีผู้ประเมินอิสระ |
Status |
ตีพิมพ์แล้ว |
Level of Publication |
นานาชาติ |
citation |
false |
Part of thesis |
true |
Attach file |
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Citation |
0
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