Research Title |
Catalytic Performance of Acid Catalysts for Sorbitol Dehydration to Isosorbide |
Date of Distribution |
29 October 2020 |
Conference |
Title of the Conference |
The 9th Joint Conference on Renewable Energy and Nanotechnology (JCREN 2020) |
Organiser |
Khon Kaen University |
Conference Place |
“ONLINE” conference via the Zoom meeting |
Province/State |
ขอนแก่น |
Conference Date |
28 October 2020 |
To |
29 October 2020 |
Proceeding Paper |
Volume |
2020 |
Issue |
9 |
Page |
64 |
Editors/edition/publisher |
|
Abstract |
This research studied dehydration of sorbitol in aqueous solution to isosorbide over heterogeneous catalysts (Amberlyst-15, Purolite CT269, and H-beta) and a homogeneous catalyst (sulfuric acid). The dehydration of sorbitol was carried out in a high-pressure reactor under a nitrogen gas atmosphere at a fixed initial pressure of 20 bars. It was found that the Purolite CT269 catalyst gave the highest sorbitol conversion of 100% and an isosorbide selectivity of 42% after 6 h at 180 °C. The results showed that an increase in the reaction temperature gave rise to sorbitol conversion. However, the solid-compound was formed during the reaction at high temperature by polymerization of the product. The high acidity could catalyze the dehydration process; however, strong acid such as sulfuric acid gave low selectivity to isosorbide. Thus, the acidity of the catalyst plays a vital role in catalytic performance for the sorbitol dehydration to isosorbide |
Author |
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Peer Review Status |
ไม่มีผู้ประเมินอิสระ |
Level of Conference |
นานาชาติ |
Type of Proceeding |
Abstract |
Type of Presentation |
Oral |
Part of thesis |
true |
Presentation awarding |
false |
Attach file |
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Citation |
0
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