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Publication
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| Research Title |
HIGH-QUALITY DEOXYGENATED PYLORITIC OIL BY USING METHANOL AS AN IN-SITU HYDROGEN DONOR PYLORISIS OIL FROM PYROLYTIC CATALYSIS CRACKING OF WASTE COOKING OIL. |
| Date of Distribution |
4 May 2023 |
| Conference |
| Title of the Conference |
2023 International Conference on Environmental Quality Concern, Control and Conservation,(EQC3) |
| Organiser |
National Kaohsiung University of Science and Technology (Nanzi Campus) |
| Conference Place |
National Kaohsiung University of Science and Technology (Nanzi Campus) |
| Province/State |
Kaohsiung |
| Conference Date |
4 May 2023 |
| To |
6 May 2023 |
| Proceeding Paper |
| Volume |
2023 |
| Issue |
1 |
| Page |
84 |
| Editors/edition/publisher |
- |
| Abstract |
The aim of the work is to upgrade pyrolysis oil (PO) from the pyrolytic catalysis cracking process (PCC) to reduce acidity and oxygen contents by using an in-situ hydrodeoxygenation process using a methanol donor in the hydrodeoxygenation process. The reaction condition was tested at various nickel loading (0, 3, 6, 9, and 12 wt%) on HZSM-5 (SiO2/Al2O3 = 40) and using temperatures at 230 °C and times 6 h. to study the effect of different nickel loading in the reaction. The prepared catalyst through the incipient wetness impregnation (IWI) method. Moreover, nickel (Ni0), reduced from the former catalysts, was also studied. The reduced oxidation state of Ni (II) to get nickel (Ni0), Where the hydrogen atoms on the nickel atoms were first absorbed when the H2 was first split apart. The fracture of the nickel-oxygen link was followed by the migration of hydrogen atoms, which led to the final dehydration of H2O and the formation of nickel-metal. was operated via a horizontal tube furnace at a temperature of 550 °C for 5 h under an atmospheric of 10% H2 mixed with 90% N2. The physical and chemical properties of the catalysts were characterized by TGA, XRF, N2 adsorption-desorption, XRD, FTIR, XPS, XANES, XAS, FE-SEM, and EDS. The analysis of upgrading oil products by many techniques such as Viscosity (ASTM D445 D240), Density (ASTM D1480-07), and HHV by calculated from the elemental analysis CHNO. In addition, FTIR, CHNO, GC-MS, and TGA were also applied to investigate. The best upgrading oil was distilled following (ASTM D86) to separate bio-gasoline, bio-kerosene, and bio-diesel. The acidity, Viscosity, Density, HHV, and total acid number (TAN) (ASTM D664) were done to compare bio-fuel before and after upgrading. The result of the work was optimal Ni loading was about 12% giving the lowest oxygen content was 82% compared with raw material pyrolytic oil from pyrolytic catalysis cracking (PCC) in upgrading oil products. |
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| Peer Review Status |
ไม่มีผู้ประเมินอิสระ |
| Level of Conference |
นานาชาติ |
| Type of Proceeding |
Abstract |
| Type of Presentation |
Oral |
| Part of thesis |
true |
| Presentation awarding |
false |
| Attach file |
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| Citation |
0
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Journal Publication
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