| Title of Article |
Chemical Surface Analysis on Post-Thermal Treatment of the K-OMS-2 Catalysts and Catalytic Oxidation Efficiency at Low Temperature |
| Date of Acceptance |
24 April 2019 |
| Journal |
| Title of Journal |
Sains Malaysiana |
| Standard |
SCOPUS |
| Institute of Journal |
Faculty of Science and Technology Universiti Kebangsaan Malaysiaogy Universiti Kebangsaan Malaysia |
| ISBN/ISSN |
|
| Volume |
48 |
| Issue |
7 |
| Month |
๋July |
| Year of Publication |
2019 |
| Page |
1447-1457 |
| Abstract |
The effect of calcination temperature on the physical and chemical properties of cryptomelane (K-OMS-2) was investigated. The K-OMS-2 was synthesized via a hydrothermal method and calcined at 200-600ºC. The catalytic activities of the K-OMS-2 samples were tested in packed bed reactor (PBR) on toluene oxidation. The physical and chemical properties were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), specific surface area computed by Brunauer-Emmett-Teller (BET) equation, Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure (XANES) techniques. The increasing of the calcination temperature from 200-600ºC led to transform the phases from MnO2 to Mn2O3. The morphology of K-OMS-2 which observed in a nest-like type could promote the catalytic activity. With increasing the calcination temperature, the amount of Oads/Olatt molar ratio slightly increased whereas OH vibrations analyzed by FTIR insignificantly increased. The comparison of interaction effect indicated that the Oads/Olatt molar ratio played an important role in the oxidation performance more than the Mn3+/Mn4+ molar ratio. |
| Keyword |
oxidation state; thermal catalysis; toluene oxidation; VOCs removal; XPS |
| Author |
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| Reviewing Status |
มีผู้ประเมินอิสระ |
| Status |
ตีพิมพ์แล้ว |
| Level of Publication |
นานาชาติ |
| citation |
false |
| Part of thesis |
true |
| Attach file |
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| Citation |
0
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Publication
Journal Publication
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