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Publication
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| Title of Article |
Coexistence of Naked-Eye Mechanochromism, Vapochromism, and Thermochromism in a Soft Crystalline Layered Nickel(II) Coordination Polymer |
| Date of Acceptance |
3 November 2021 |
| Journal |
| Title of Journal |
Inorganic Chemistry |
| Standard |
SCOPUS |
| Institute of Journal |
ACS Publications |
| ISBN/ISSN |
10.1021/acs.inorgchem.1c02875 |
| Volume |
2022 |
| Issue |
60 |
| Month |
พฤศจิกายน |
| Year of Publication |
2021 |
| Page |
18242–18250 |
| Abstract |
Chromic materials have the potential to be used in a
variety of applications, including memory devices and sensors. Despite fact that stimuli-responsive chromic materials have been widely
reported to date, fabricating chromic materials that can be responsive to multiple external stimuli remains a challenge. Herein, a new multistimuli responsive chromic coordination polymer of {[Ni(pzt)2(H2O)2](H2O)(DMF)}n (1); Hpzt = 5-(3-pyridyl)-1,3,4-oxadiazole-2-thiol, was successfully synthesized. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a soft crystalline 3-dimenional (3D) supramolecular framework generated by weakly interlayered stacking interactions between 2D coordination polymers.
Compound 1 revealed unprecedented naked-eye mechanochromism, vapochromism, and thermochromism in response to multiple external
stimuli including manual grinding, amine and alcohol vapors, and heat, respectively. The chromism related to the structural feature was clarified by SC-XRD, PXRD, TGA, elemental analysis, and spectroscopic techniques. |
| Keyword |
Amines, Crystal structure, Diffraction, Ligands, Molecules |
| Author |
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| Reviewing Status |
มีผู้ประเมินอิสระ |
| Status |
ตีพิมพ์แล้ว |
| Level of Publication |
นานาชาติ |
| citation |
false |
| Part of thesis |
true |
| Attach file |
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| Citation |
0
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Journal Publication
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